Studies related to: bark extractives of western white pine; and synthesis of indole alkaloids

Günter Klaus Eigendorf
Part I of this thesis describes the structural elucidation of eleven triterpenes isolated from the benzene extract of Western white pine (Pinus monticbla Dougl.) bark. Chemical and detailed spectroscopic investigations revealed the presence of a common tetracyclic A9(ll)-lanostene skeleton in all of the investigated materials. Structural variations were found at the C3 position and in the side chain at C17. The following assignments have been made: compound I, 33~methoxy-5a-lanost-9(ll)-en-24S,25-diol (43); compound II, the corresponding 33-hydroxy...
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