Manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols via alkoxy radicals: dataset

Benjamin D W Allen, Deepak Mishra, Alex C Seastram, Tom McBride, Thomas Wirth, Duncan L Browne & Louis C Morrill
A manganese-catalyzed electrochemical deconstructive chlorination of cycloalkanols has been developed. This electrochemical method provides access to alkoxy radicals from alcohols and exhibits a broad substrate scope, with various cyclopropanols and cyclobutanols converted into synthetically useful β- and γ-chlorinated ketones (40 examples). Furthermore, the combination of recirculating flow electrochemistry and continuous inline purification was employed to access products on a gram scale. Analysis of reaction products from this methodology resulted in the following data: 1H, 19F...
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