Materials Data on NpAsS by Materials Project

Kristin Persson
NpAsS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. Np5+ is bonded in a 5-coordinate geometry to four equivalent As3- and five equivalent S2- atoms. All Np–As bond lengths are 3.07 Å. There are four shorter (2.79 Å) and one longer (2.80 Å) Np–S bond lengths. As3- is bonded to four equivalent Np5+ and four equivalent As3- atoms to form distorted AsNp4As4 hexagonal bipyramids that share corners with...
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