Bi2Pt is Pyrite structured and crystallizes in the cubic Pa-3 space group. The structure is three-dimensional. Pt2- is bonded to six equivalent Bi1+ atoms to form corner-sharing PtBi6 octahedra. The corner-sharing octahedral tilt angles are 62°. All Pt–Bi bond lengths are 2.82 Å. Bi1+ is bonded in a trigonal planar geometry to three equivalent Pt2- atoms.
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