Materials Data on P4(SO2)3 by Materials Project

Kristin Persson
P4(SO2)3 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4(SO2)3 clusters. there are four inequivalent P+4.50+ sites. In the first P+4.50+ site, P+4.50+ is bonded to one S2- and three O2- atoms to form distorted corner-sharing PSO3 tetrahedra. The P–S bond length is 1.88 Å. There is one shorter (1.62 Å) and two longer (1.64 Å) P–O bond length. In the second P+4.50+...
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