Materials Data on NaAl(H2N)4 by Materials Project

Kristin Persson
NaAl(NH2)4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional and consists of four ammonia molecules, four hydrogen molecules, and one NaAl(NH)3 framework. In the NaAl(NH)3 framework, Na1+ is bonded in a 3-coordinate geometry to two N3- and one H1+ atom. There are one shorter (2.35 Å) and one longer (2.41 Å) Na–N bond lengths. The Na–H bond length is 2.16 Å. Al3+ is bonded in a distorted T-shaped geometry to two equivalent...
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