Ag2O is trigonal omega structured and crystallizes in the trigonal P-3m1 space group. The structure is two-dimensional and consists of one Ag2O sheet oriented in the (0, 0, 1) direction. Ag1+ is bonded in a 3-coordinate geometry to three equivalent O2- atoms. All Ag–O bond lengths are 2.35 Å. O2- is bonded to six equivalent Ag1+ atoms to form edge-sharing OAg6 octahedra.
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