Materials Data on V2CoO7 by Materials Project

Kristin Persson
V2CoO7 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. there are four inequivalent V5+ sites. In the first V5+ site, V5+ is bonded to four O2- atoms to form VO4 tetrahedra that share corners with three CoO6 octahedra and a cornercorner with one VO5 trigonal bipyramid. The corner-sharing octahedra tilt angles range from 42–57°. There are a spread of V–O bond distances ranging from 1.62–1.85 Å. In the second V5+ site, V5+...
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