Supramolecular networks stabilise and functionalise black phosphorus

Vladimir Korolkov
The limited stability of the surface of black phosphorus (BP) under atmospheric conditions is a significant constraint on the exploitation of this layered material and its few layer analogue, phosphorene, as an optoelectronic material. Here Wwe show that the surface of black phosphorus (BP) supports the formation of supramolecular networks stabilised by hydrogen bonding can be formed on BP, and that these monolayer-thick films can passivate the BP surface and inhibit oxidation under ambient conditions....
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