Investigation into the magnetic and the structural properties of two low-dimensional antiferromagnets TiPO4 and CrOCl

Patrick Gerald Reuvekamp
Titanium (III) phosphate TiPO4 (3d1 electronic configuration with S = 1/2) is a one-dimensional quantum antiferromagnet exhibiting non-conventional spin-Peierls behaviour at low temperatures. Chromium oxychloride CrOCl (3d3 electronic configuration with S = 3/2) is a two-dimensional antiferromagnet consisting of ferromagnetic spin chains interconnected by competing anti and ferromagnetic spin exchanges interactions. The magnetic and the structural properties of these compounds are intimately related via magnetoelastic coupling. Incommensurate and commensurate phases are observed at low temperatures...
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