Excited electronic states of flavin-containing coenzyme models

Friedemann Gückel, Dieter Schweitzer, Katja Becker, Rolf Heiner Schirmer, Matthias F. Zipplies & Heinz A. Staab
In order to gain further insight into the physical basis of flavin-catalyzed reactions, the interactions of a flavin with a second flavin and with other aromatic ring systems were studied. For this purpose compounds through 1 were synthesized These compounds contain the interacting units in defined geometric orientation. A monomeric flavin and glutathione reductase a flavoenzyme of known active-site chemistry, were included as reference molecules. The present report deals with excited triplet states of the...
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