Methylenphosphanyl-Komplexe von Chrom, Molybdän, Wolfram, Eisen und Nickel: Synthese und Reaktionen

Edgar Niecke, Hans-Jürgen Metternich, Martin Nieger, Dietrich Gudat, Peter Wenderoth, Wolfgang Malisch, Christoph Hahner & Wolfgang Reich
The reaction of the functionalized P/C double bond systems X-P=C(R)SiMe3 [R = SiMe3 and X = Cl (1a), Cp* (5a) or R = Ph and X = Br (1b), Cp* (5b)] with alkali carbonylmetallates or carbonyl complexes of group 6, 8, and 10 metals leads to the formation of the transition metal-substituted phosphaalkenes [{M}-P=C(R)SiMe3 3a-j and 4a-i], in which the P-C fragment acts as a one-electron donor. Depending on the nucleophilicity of the transition metal...
This data repository is not currently reporting usage information. For information on how your repository can submit usage information, please see our documentation.