The mechanism of adsorption of sulfides on gold(111).

Deyu. Qu
In this thesis, we present the electrochemical and spectroscopic characterization of the monolayer on a Au(111) single crystal formed by alkanethiols, dialkyldisulfides and dialkylsulfides. We found that all these organic sulfur compounds adsorb dissociatively and form a monolayer of thiolates. We also study the monolayer formed by a cyclic sulfide, pentamethylene sulfide. We found that this sulfide forms a monolayer of an aldehyde terminated thiolate. We suggest that the sulfide is oxidatively dissociated by molecular...
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