Synthesis, and characterization of low-valent titanium complexes.

Ludmila. Scoles
The chemistry of low-valent titanium is poorly developed apart from ubuquitous cyclopentadienyl derivatives. Among the possible supporting ligands for stabilizing low-valent transition-metal complexes, are alkylamides. By introducing bulky amides such as R$\rm \sb2 N\sp-$ $\rm (R\ =\ Me\sb3 Si,\ \sp{i}Pr,\ Cy)$ in the chemistry of Ti(III), we have opened a new field in the coordination and organometallic chemistry of this early transition metal. Synthetic methodology is focused on the preparation of novel bis(amido) Ti(III) complexes...
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