A piezokinetic study of the solvolyses of benzyl chlorides.

Reginald L. Martin
Rate constants for the solvolysis of benzyl chloride, p-methyl benzyl chloride, p-nitro benzyl chloride and p-chloro benzyl chloride were determined at four pressures at 50°C in an acetone-water mixture containing 0.1407 mole fraction acetone. Rate constants for the solvolysis of p-methyl benzyl chloride in four acetone-water mixtures were also determined at four pressures at 50°C. The partial molar volumes of this latter compound were determined in these same acetone-water mixtures at 25°C. The log10k-pressure data...
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