Rhodium catalyzed hydroformylation: Adventures in heterogeneous and recyclable systems

S. Christine Bourque
The synthesis of dendritic ligands supported on silica gel and polymers, and their use in the rhodium catalyzed hydroformylation reaction is presented in this thesis. In building a softer, more organic moiety on the surface of a heterogeneous support, the potential of uniting the advantages of heterogeneous catalysis with that of homogeneous systems is explored. The synthesis of polyamidoamine (PAMAM) dendrimers anchored on silica, via the iterative additions of methylacrylate and ethylenediamine to aminopropyl silica,...
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