Synthesis, Kinetics, and Mechanism of Catalytically Active Aminic Radical-Trapping Antioxidants & Development of the Fluorometric and Spectrophotometric Tools Used in Their Analysis

Evan Haidasz
Amine and nitroxide based radical-trapping antioxidants (RTAs) have long been known to display remarkable efficacy as inhibitors of hydrocarbon autoxidation. Their unique ability to catalytically trap the chain-carrying peroxyl radicals responsible for oxidative degradation of organic materials has led to their widespread use in petroleum-derived materials. While a great deal of research has been done to understand and expand upon this reactivity, little improvement in the chemistry behind diarylamine and nitroxide RTAs has emerged. In...
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