Transition metal catalyzed carbonylations of vinylsilanes, allyl sulfides and related systems.

Cathleen Marie. Crudden
It has been demonstrated that the zwitterionic rhodium complex (Rh zw), [Rh(COD)+]BPh4-, is an effective catalyst for the hydroformylation of vinylsilanes. With vinyltrimethylsilane, the branched aldehyde could be obtained as the major aldehyde isomer if the CO:H2 ratio was 1:2 (total pressure = 200 psi). Under these conditions, 20-40% isolated yield was obtained and the low Yield of these reactions was confirmed by experiments performed in deuterated solvents. The hydroformylation of vinyltriethylsilane, on the other...
This data repository is not currently reporting usage information. For information on how your repository can submit usage information, please see our documentation.