π-Extended quinolinioum derivatives: synthesis, properties, classification

Sviatoslav Batsyts
In this work, different quinoline derivatives were synthesized (Scheme 1). Furthermore, the analysis of the obtained information led to an adjustment of the classification of mesomeric betaines. Scheme 1: Various examples of methyl quinolinium derivatives The synthesis of the pi-conjugated methyl quinolinium salts 1a-c with further analysis showed the difference between betaine precursors. DFT calculations of the corresponding betaines 2a-c helped to elucidate the behavior of both positive and negative charges in pi-conjugated systems. The...
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