Efficient Creation and Morphological Analysis of ABC Triblock Terpolymer Libraries

Elizabeth Murphy, Yan-Qiao Chen, Kaitlin Albanese, Jacob Blankenship, Allison Abdilla, Morgan Bates, Cheng Zhang, Christopher Bates & Craig Hawker
Multiblock copolymers with increasingly complex block sequences—for example, triblock terpolymers—offer unique opportunities to create nanostructured materials, but this potential has been hindered by a vast design space that complicates the exploration of structure–property relationships. Here, we report a versatile and scalable strategy to separate parent ABC and isomeric ACB triblock terpolymers into libraries of fractionated samples spanning a wide range of compositions. Using a combination of controlled polymerization and automated chromatography, the synthesis and separation...
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