Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle

Angel E. Kaifer, Vaclav Havel, Vladimir Sindelar & Marek Necas
A supramolecular complex between benzoates and a bambusuril crystallizes out immediately after mixing in chloroform but only in the presence of residual water molecules. In this complex each of the two portals of the macrocycle is occupied by one benzoate. Carboxylate groups are connected through hydrogen bo
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