An Approximate Analytical Solution for Multi-mono-valent Cation Exchange Reactive Transport in Groundwater

Javier Samper, Changbing Yang & Javier Samper
Cation exchange in groundwater is one of the dominant surface reactions. Mass transfer of cation-exchanging pollutants in groundwater is highly nonlinear. This makes difficult to derive analytical solutions for multication exchange reactive transport which are of interest for stochastic analyses of multicomponent reactive transport. Dou and Jin (1996) used the method of characteristics with a special treatment of shock waves and worked out a closed-form formulation for 1-D transport coupled to binary homovalent ion exchange....
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