Synthesis of carbonylic derivatives from alkylaromatics by a photocatalytic oxidation using Fe/Ti-pillared clays.

Houria REZALA, Jose Luis VALVERDE, Amaya ROMERO, Alessandra MOLINARI & Andrea MALDOTTI
A pillared montmorillonite containing iron doped titania (Fe/Ti-PILC) has been prepared from a natural clay. This material has been characterized by X-ray diffraction, nitrogen adsorption, temperature programmed desorption of ammonia, inductively coupled plasma atomic emission spectroscopy, atomic absorption and diffuse reflectance UV-VIS spectroscopy. The doped material was a robust photocatalyst able to oxidize liquid alkylaromatics to the corresponding carbonylic derivatives, using O2 as the oxidizing species, at mild pressure and temperature conditions. Accumulation of valuable...
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