This paper reports a study on conductive textiles prepared by chemical oxidative polymerization of anizidine using ammonium persulfate as an oxidant. A two-step process is adopted. The morphology of treated and control cotton were studied by SEM. The study has shown the polymer granules on the treated fabric. Polyanizidine presented into treated cotton was confirmed by ATR-FTIR and WAXD. The thermal properties were studied by ATG and DSC confirming polymer deposition into cotton fabric.