Synthesis and characterization of iron-clathrochelates and their applications in materials science

José Luis Bila
This thesis focuses on the design and the synthesis of mono- and dinuclear iron clathrochelate complexes and their applications in materials science. Dinuclear iron clathrochelate complexes can be synthesized in different oxidation states: i. as negatively charged FeII-FeII complexes or ii. as neutral FeII-FeIII complexes. These compounds display interesting magnetic properties. The negatively FeII-FeII complexes are antiferromagnetic, whereas the neutral FeII-FeIII complexes are paramagnetic. In addition, an interconversion between the two redox states can be...
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