ON THE PHOTOBROMINATION OF CINNAMIC ACID IN ULTRAVIOLET LIGHT OF 254μμ.

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The kinetics and mechanism of the bromination of cinnamic acid in ultraviolet light of 254μμ in solution of carbon tetrachloride have been studied in details. Results which have been found are quite different from those found with visible light by various workers. The reaction is unimolecular with respect to bromine as well as with respect to cinnamic acid. The velocity constant is directly proportional to the intensity of radiation absorbed by cinnamic acid and is...
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