The magnetic structure of perovskite like coordination polymers: {[Cu(HCOO)2(µ-pyrimidine)]}n and {[Cu(HCOO)2NO3]H2N(CH3)2}n

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This study is designed to identify relationships between structure and magnetic properties characteristic of coordination polymers (CPs), specifically in the model system {[Cu(HCOO)3]H2N(CH3)2}n. By determining the magnetic structure of two related CPs, in which a single magnetic pathway was systematically modified by substituting an HCOO- linker with topologically equivalent pyrimidine and NO3- ligands, respectively, we aim to address factors that tune the strength and nature of magnetic super-exchange. Moreover, the orientation of the magnetic moments...
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