Group 6 Metal-Oxo and -Alkylidyne Complexes with High Reactivity Derived from π-Antibonding Orbitals

Hunter Baksa Vibbert
Photoredox catalysis has become a useful synthetic technique to make and break chemical bonds in chemical structures relevant to medicinal chemistry and renewable energy. Few general approaches, however, have been reported that can prepare synthetically useful organic radicals whose parent molecules are reduced negative of –2.6 V (vs FeCp20/+). One such approach to accessing these molecules is to design photoredox chromophores that can directly prepare these radical species. The central hypothesis investigated here is that...
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