Structural transformation from 1D to 3D in [K(µ5-L1).H2O]n (L1 = 2,4-dinitrobenzoate) by nitro group coordination: Comparison with theoretical and Hirshfeld surface calculations

Lyle Isaacs &
Reaction of KOH with 2,4-Dinitrobenzoic acid (L1H) in the presence of acetonitrile-water mixture yielded product [K(μ5-L1).H2O]n resulted in a dramatic structural transformation into 3D polymeric complex. The observed structural transformation is arising from the coordination through carboxylate as well as both nitro groups. This polymeric complex has been solved in triclinic centrosymmetric space group (Pī) and characterised by elemental analysis, FT-IR spectroscopy, powder X-ray diffraction analysis and single-crystal diffraction analysis. This complex attains high...
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