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Lecture 17. Introduction to 2D NMR Spectroscopy

James Nowick
UCI Chem 203 Organic Spectroscopy (Fall 2011) Lec 17. Organic Spectroscopy -- Introduction to 2D NMR Spectroscopy Instructor: James Nowick, Ph.D. Description: This is a graduate course in organic spectroscopy, focusing on modern methods used in structure determination of organic molecules. Topics include mass spectrometry; ultraviolet, chiroptical, infrared, and nuclear magnetic resonance spectroscopy.

Lecture 14. Alkali Organometallics (Pt. II)

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 14. Organic Reaction Mechanism -- Alkali Organometallics -- Part 2 Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lecture 17. Enols, Enamines, and Enolates

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 17. Organic Reaction Mechanism -- Enols, Enamines and Enolates CORRECTION AT 47m09s (as annotated) - "should be (E+N) IS GREATER THAN -5" Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions,...

Lecture 15. Addition of E+ to C=C

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 15. Organic Reaction Mechanism -- Addition of Electrophilic to C=C Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lecture 09. Pt 2. Addition to Sigma Star (σ*)

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 09. Organic Reaction Mechanism -- Addition to Sigma Star (σ*) Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lecture 07. Neighboring Groups

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 07. Organic Reaction Mechanism -- Neighboring Groups Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lecture 04. Selectivity

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 04. Organic Reaction Mechanism -- Selectivity Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lecture 01. Arrow Pushing. Part 2

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 01. Organic Reaction Mechanism -- Arrow Pushing -- Part 2 Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lec 14. Alkali Organometallics (Pt. III) & Lec 15

David Van Vranken
UCI Chem 201 Organic Reaction Mechanisms I (Fall 2012) Lec 14 and Lec 15. Organic Reaction Mechanism -- Alkali Organometallics (Part 3) & Addition of E+ to C=C Instructor: David Van Vranken, Ph.D. Description: Advanced treatment of basic mechanistic principles of modern organic chemistry. Topics include molecular orbital theory, orbital symmetry control of organic reactions, aromaticity, carbonium ion chemistry, free radical chemistry, the chemistry of carbenes and carbanions, photochemistry, electrophilic substitutions, aromatic chemistry.

Lecture 09. Vibrations in Molecules

Rachel Martin
UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013) Lec 09. Molecular Structure & Statistical Mechanics -- Vibration in Molecules. Instructor: Rachel Martin, Ph.D. Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Index of Topics: 0:00:08 Methane-Vibrations 0:11:56 Vibrational Modes 0:13:35 IR Spectrum of Methane 0:15:18 Harmonic Oscillator Energy Levels 0:18:24 Vibrational and Rotational...

Lecture 05. Rotational Spectroscopy Pt. I.

Rachel Martin
UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013) Lec 05. Molecular Structure & Statistical Mechanics -- Rotational Spectroscopy -- Part 1. Instructor: Rachel Martin, Ph.D. Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Index of Topics: 0:00:55 Which Orbitals can Form Pi Bonds 0:06:12 Symmetry Properties of Functions 0:08:33 H2 Molecular Orbitals 0:09:00...

Lecture 04. Group Theory Applications.

Rachel Martin
UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013) Lec 04. Molecular Structure & Statistical Mechanics -- Group Theory Applications. Instructor: Rachel Martin, Ph.D. Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Index of Topics: 0:00:07 Bonding 0:15:38 Which Orbitals Form the Sigma Bond? 0:20:44 Which Orbitals Can Form Pi Bonds? 0:26:53 Out of...

Lecture 23. Partition Functions Pt. 1

Rachel Martin
UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013) Lec 23. Molecular Structure & Statistical Mechanics -- Partition Functions -- Part 1. Instructor: Rachel Martin, Ph.D. Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Index of Topics: 0:02:51 Rotational Spectrum of HCl 0:03:53 Molecular Partition Function 0:22:25 2-Level System Partition Function 0:31:12 Particle in...

Lecture 17. NMR (Pt. II)

Rachel Martin
UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013) Lec 17. Molecular Structure & Statistical Mechanics -- NMR -- Part 2. Instructor: Rachel Martin, Ph.D. Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Index of Topics: 0:02:54 Zeeman Effect 0:06:46 High Field Magnets for NMR/MRI 0:09:09 Nuclear Zeeman Effect 0:11:23 Nuclear Spin Hamiltonian 0:13:28...

Lecture 16. Fourier Transforms, NMR Intro

Rachel Martin
UCI Chem 131B Molecular Structure & Statistical Mechanics (Winter 2013) Lec 16. Molecular Structure & Statistical Mechanics -- Fourier Transforms, NMR Intro -- Part 1. Instructor: Rachel Martin, Ph.D. Description: Principles of quantum mechanics with application to the elements of atomic structure and energy levels, diatomic molecular spectroscopy and structure determination, and chemical bonding in simple molecules. Index of Topics: 0:01:33 Fourier Series 0:18:45 X-Ray Crystallography 0:23:07 Ion Channels 0:25:12 Pulsed NMR 0:28:48 Free Induction...

Which is best? SQL Server vs Postgres

Rob Sullivan
Falling in love with the free spirit of Postgres Using the StackOverFlow datasets, we'll ditch all the drama of a Microsoft stack and convert from SQL Server to Postgres on Windows. Once we do that, we'll migrate our entire DB and Web App from Microsoft to Linux using Postgres and Mono with as few code changes as possible. Having the StackOverFlow dataset loaded into SQL Server and a mock StackOverFlow app in ASP.NET MVC3, we...

Temporal Data Management in PostgreSQL: Past, Present, and Future

Jeff Davis
Range Types and Temporal: Past, Present, and Future Range Types didn't exist before, why do we need them now? How do they work? Why is "Temporal" important if we already have timestamps? How do we apply these concepts before deploying PostgreSQL 9.2? What's left to be done, and what solutions are in the works? I'll be asking the audience these questions, so -- Err... I mean: I will be answering these questions during the talk....

Runtime Process Infection (part 1)

Shawn Webb
This presentation will instruct participants on how to inject arbitrary code into a process during runtime. Writing malware on Linux isn't an easy task. Anonymously injecting shared objects has been a frightful task that no one has publicly implemented. This presentation will show how and why malware authors can inject shared objects anonymously in 32bit and 64bit linux and 64bit FreeBSD. The presenter will be releasing a new version of a tool called libhijack. libhijack...

Managing FreeBSD at scale

Allan Jude
Detailed discussion of ScaleEngine's production implementation of puppet on FreeBSD to manage many heterogeneous servers across the globe, with 70+ servers at 26 data centres in 10 countries deployed in a number of different roles (Web Hosting Cluster, HTTP Accelerator, HTTP CDN, Live Video, On-Demand Video, GSLB DNS) our needs cover a large swath of the capabilities of any management system. It is common for sysadmins to jump straight to cloud providers if immediate scale...

Call your NetBSD

Pierre Pronchery
After focusing on improving NetBSD support for tablet hardware, NetBSD enthusiast and DeforaOS developer Pierre Pronchery (khorben@) is working on running NetBSD on smartphone hardware, with the OMAP-based Nokia N900 as the main target. After a quick summary of the different steps taken, he will introduce the user interface, installation procedure and underlying specificities to this setup. If all goes well, he will even be able to give a call! NetBSD is a very portable...

Benchmarking FreeBSD

Ivan Voras
System optimization and tuning is tricky business. Benchmarking such systems is even more complicated as the number of things which can go wrong at doubles at the least. FreeBSD is best known for its killer features, but it also includes over 2500 sysctls, most of which can be tuned to do something interesting. This talk aims to give an overview of some of the more interesting things which can be tuned in FreeBSD, and advice...

Open Source Meets the Commercial World

Dan Langille & Eric Allman
Bambi Meets Godzilla: They Elope The world of open source and the world of commercial software intersect in profound and sometimes surprising ways. In some sense the two are like oil and water, but in other ways they can build on each other. This talk describes some of those differences — and ways they can enhance one another — using the sendmail open source mail transfer agent and Sendmail, Inc. as a case study.

Mozilla on OpenBSD

Landry Breuil
Maintaining the port of Firefox to OpenBSD is an interesting challenge, since the web & its related technologies are evolving faster and faster, and third-party OS are struggling more and more to keep up the pace with a fast-moving target such as Mozilla. I'll explain how i got caught into this by accident in the beginning of 2010, what are the key things to know about Mozilla development when coming from another big OSS project,...

Case Study: Switching from Linux to FreeBSD

Paul Chvostek
This talk will outline the strategy used to migrate a small Canadian software company's Linux-based server infrastructure to FreeBSD. Part advocacy-strategy and part best-practices, the hope is that you'll come away with some extra tools to promote implementation of FreeBSD in your workplace. ExperiencePoint is a small (20 person) Canadian company that creates training simulations as web applications. The business is wholly dependent on its web server infrastructure for delivering its product. In 2011, I...

Lecture 9. The second and third laws of thermodynamics, Part III

Donald R. Blake
UCI Chem 1B is the second quarter of General Chemistry and covers the following topics: properties of gases, liquids, solids; changes of state; properties of solutions; stoichiometry; thermochemistry; and thermodynamics. Index of Topics: 0:01:18 Spontaneous Process 0:04:12 Second Law of Thermodynamics 0:05:25 Gibbs Free Energy 0:22:07 Free Energy: Temperature 0:23:26 Quiz: Free Energy and Temperature 0:25:07 Quiz: Triple Point 0:26:19 Quiz: Spontaneous Reaction 0:28:23 Delta G and Delta S 0:37:52 Example: Combustion of Magnesium 0:40:55...

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