42 Works

Real-time analysis of multiple anion mixtures in aqueous media using a single receptor

Vaclav Havel, Vladimir Sindelar & Mirza Arfan Yawer
Bambusuril macrocycles allow qualitative and quantitative sensing of anion mixtures in water using 1H NMR spectroscopy.

Novel Supramolecular Hosts Based on Linear and Cyclic Oligomers of Glycoluril

Marek Stancl, Jan Svec & Vladimir Sindelar
We report here on supramolecular objects containing glycoluril units and functioning as host molecules. The present paper contains a detailed discussion on the synthetic approaches leading to methyle...

Synthesis and supramolecular properties of glycoluril tetramer

Vladimir Sindelar, Marek Necas, Laura Gilberg, Lukas Ustrnul & Marek Stancl
(2014). Synthesis and supramolecular properties of glycoluril tetramer. Supramolecular Chemistry: Vol. 26, Eighth International Symposium of Macrocyclic and Supramolecular Chemistry (ISMSC-8), pp. 168-172.

Global maps of current (1979-2013) and future (2061-2080) habitat suitability probability for 1,485 European endemic plant species

Robin Pouteau, Idoia Biurrun, Caroline Brunel, Milan Chytrý, Wayne Dawson, Franz Essl, Trevor Fristoe, Rense Haveman, Carsten Hobohm, Florian Jansen, Holger Kreft, Jonathan Lenoir, Bernd Lenzner, Carsten Meyer, Jesper Erenskjold Moeslund, Jan Pergl, Petr Pyšek, Jens-Christian Svenning, Wilfried Thuiller, Patrick Weigelt, Thomas Wohlgemuth, Qiang Yang & Mark Van Kleunen
Aims: The rapid increase in the number of species that have naturalized beyond their native range is among the most apparent features of the Anthropocene. How alien species will respond to other processes of future global changes is an emerging concern and remains largely misunderstood. We therefore ask whether naturalized species will respond to climate and land-use change differently than those species not yet naturalized anywhere in the world. Location: Global Methods: We investigated future...

Disentangling responses to natural stressor and human impact gradients in river ecosystems across Europe

Rachel Stubbington, Romain Sarremejane, Alex Laini, Núria Cid, Zoltán Csabai, Judy England, Antoni Munné, Tom Aspin, Núria Bonada, Daniel Bruno-Collados, Sophie Cauvy-Fraunie, Richard Chadd, Claudia Dienstl, Pau Fortuño, Wolfram Graf, Cayetano Gutiérrez-Cánovas, Andy House, Ioannis Karaouzas, Eleana Kazila, Andrés Millán, Maria Morais, Petr Pařil, Alex Pickwell, Marek Polášek, David Sánchez-Fernández … & Thibault Datry
1. Rivers are dynamic ecosystems in which both human impacts and climate-driven drying events are increasingly common. These anthropogenic and natural stressors interact to influence the biodiversity and functioning of river ecosystems. Disentangling ecological responses to these interacting stressors is necessary to guide management actions that support ecosystems adapting to global change. 2. We analysed the independent and interactive effects of human impacts and natural drying on aquatic invertebrate communities—a key biotic group used to...

Binding of bambusuril with bipyridinium guests in water

Kristina Sleziakova, Mehdi Rashvand Avei, Angel E. Kaifer & Vladimir Sindelar
(2018). Binding of bambusuril with bipyridinium guests in water. Supramolecular Chemistry: Vol. 30, SI: ISMSC, pp. 832-837.

Supramolecular binding and release of sulfide and hydrosulfide anions in water

Julián Vázquez Gonzálvez & Vladimir Sindelar
Bambusuril macrocycles bind and release sulfide and hydrosulfide anions in water.

Supramolecular Storage and Controlled Photorelease of an Oxidizing Agent using a Bambusuril Macrocycle

Vladimir Sindelar, Edoardo Torti, Václav Havel, Mirza A. Yawer, Lucie Ludvíková, Michal Babiak & Petr Klán
Abstract The oxidizing ability of peroxodisulfate upon complexation inside the Bambusuril macrocycle cavity is inhibited. This dianionic agent can be released on demand from its stable 1:1 complex ...

Acyclic cucurbit[n]uril-type molecular containers: influence of glycoluril oligomer length on their function as solubilizing agents

Laura Gilberg, Ben Zhang, Peter Y. Zavalij, Vladimir Sindelar & Lyle Isaacs
A series of glycoluril molecular clips and acyclic CB[n]-type receptors are tested as solubilizing agents for insoluble drugs.

Data from: Postglacial determinants of regional species pools in alpine grasslands

Borja Jiménez-Alfaro, Wolfgang Willner, Eszter Ruprecht, Kiril Vassilev, Nevena Kuzmanovic, Renata Ćušterevska, Djordjije Milanovic, Josef Sibik, Sylvain Abdulhak, Angela Stanisci, Maria Luisa Carranza, Ariel Bergamini, Corrado Marcenó & Gianpietro Giusso Del Galdo
Aim: Alpine habitats support unique biodiversity confined to high-elevation areas in the current interglacial. Plant diversity in these habitats responds to area, environment, connectivity and isolation, yet these factors have been rarely evaluated in concert. Here we investigate major determinants of regional species pools in alpine grasslands, and the responses of their constituent species groups. Location: European mountains below 50ºN. Time Period: Between 1928 and 2019. Major Taxa Studied: Vascular plants. Methods: We compiled species...

What defines insularity for plants in edaphic islands?

Francisco Emmanuel Méndez Castro, Luisa Conti, Milan Chytrý, Borja Jimenez-Alfaro, Michal Hajek, Michal Horsák, David Zeleny, Marco Malavasi & Gianluigi Ottaviani
The Theory of Island Biogeography postulates that size and isolation are key drivers of biodiversity on islands. This theory has been applied not only to true (e.g. oceanic) islands but also to terrestrial island-like systems (e.g. edaphic islands). Recently, a debate has opened as to whether terrestrial island-like systems function like true islands. However, identifying the effect of insularity in terrestrial systems is conceptually and methodologically challenging because recognizing species source(s) and measuring isolation is...

Supplement to: Global impact of the COVID-19 pandemic on stroke care and intravenous thrombolysis

Raul Nogueira, Muhammed Qureshi, Mohamad Abdalkader, Sheila Martins, Hiroshi Yamagami, Zhongming Qiu, Ossama Mansour, Anvitha Sathya, Anna Czlonkowska, Georgios Tsivgoulis, Diana Aguiar De Sousa, Jelle Demeestere, Robert Mikulik, Peter Vanacker, James Siegler, Janika Korv, Jose Biller, Conrad Liang, Navdeep Sangha, Alicia Zha, Alexandra Czap, Christine Holmstedt, Tanya Turan, George Ntaios, Konark Malhotra … & Thanh Nguyen
Objective: The objectives of this study were to measure the global impact of the pandemic on the volumes for intravenous thrombolysis (IVT), IVT transfers, and stroke hospitalizations over 4 months at the height of the pandemic (March 1 to June 30, 2020) compared with two control 4-month periods. Methods: We conducted a cross-sectional, observational, retrospective study across 6 continents, 70 countries, and 457 stroke centers. Diagnoses were identified by their ICD-10 codes and/or classifications in...

Tight inclusion complexation of 2,7-dimethyldiazapyrenium in cucurbit[7]uril

Angel E. Kaifer, Vladimir Sindelar, Mabel A. Cejas & Fran�isco M. Raymo
The dicationic guest 2,7-dimethyldiazapyrenium is bound inside the host cucurbit[7]uril, forming a very stable inclusion complex in which the host undergoes structural distortions to accommodate the guest.

A Bambusuril Macrocycle that Binds Anions in Water with High Affinity and Selectivity

Mirza Arfan Yawer, Vaclav Havel & Vladimir Sindelar
One ring binds them all: A bambusuril macrocycle is able to selectively capture a large number of different inorganic anions in water. The high stability of the resulting inclusion complexes is due t...

Complexation of Ferrocene Derivatives by the Cucurbit[7]uril Host:  A Comparative Study of the Cucurbituril and Cyclodextrin Host Families

Woo Sung Jeon, Kwangyul Moon, Sang Hyun Park, Hyungpil Chun, Young Ho Ko, Jin Yong Lee, Eun Sung Lee, S. Samal, N. Selvapalam, Mikhail V. Rekharsky, Vladimir Sindelar, David Sobransingh, Yoshihisa Inoue, Angel E. Kaifer & Kimoon Kim
The formation of inclusion complexes between cucurbit[7]uril (CB[7]) and ferrocene and its derivatives has been investigated. The X-ray crystal structure of the 1:1 inclusion complex between ferrocene and CB[7] revealed that the guest molecule resides in the host cavity with two different orientations. Inclusion of a set of five water-soluble ferrocene derivatives in CB[7] was investigated by 1H NMR spectroscopy and calorimetric and voltammetric techniques. Our data indicate that all neutral and cationic guests form...

Data from: Facebook groups as citizen science tools for plant species monitoring

Riccardo Guarino, Emanuele Genduso, Dario Salemi & Corrado Marcenò
Species list of the vascular flora of Sicily and related plant traits analysed in the paper "Facebook groups as citizen science tools for plant species monitoring". These include: floral traits, vegetative traits, life form, plant size, traditional use (edible/healing plants only). All traits were extracted from the digital archives of the Flora of Italy (Pignatti et al. 2017-2019) except for the conservation status of species, which was taken from Raimondo et al. (2011) and from...

Data from: New drivers of the evolution of mimetic accuracy in Batesian mimics: body size, habitat stratification and geographic zone affect accuracy of myrmecomorphic spiders

Stano Pekar
Aim: The evolution and maintenance of accurate Batesian mimicry has been explained by several hypotheses built upon relaxed selection. Such selection can be influenced by ecological factors, such as habitat type or geographic distribution, which have not been considered. I investigated whether the mimetic accuracy is influenced by habitat stratification where mimics occur (ground, low vegetation, bush, tree), their body size, and geographic distribution (temperate, subtropical, tropical). Location: Worldwide Taxon: Araneae Methods: I gathered data...

Data from: Temporal turnover of the soil microbiome composition is guild-specific

Tijana Martinovic, Iñaki Odriozola, Tereza Mašínová, Barbara Bahnmann, Petr Kohout, Petr Sedlák, Kristina Merunková, Tomáš Větrovský, Michal Tomšovský, Otso Ovaskainen & Petr Baldrian
Although spatial and temporal variation are both important components structuring microbial communities, the exact quantification of temporal turnover rates of fungi and bacteria has not been performed to date. In this study, we utilized repeated resampling of bacterial and fungal communities at specific locations across multiple years to describe their patterns and rates of temporal turnover. Our results show that microbial communities undergo temporal change at a rate of 0.010-0.025 per year (in units of...

The effect of niche filtering on plant species abundance in temperate grassland communities

Josep Padullés Cubino, Irena Axmanová, Zdeňka Lososová, Martin Večeřa, Ariel Bergamini, Helge Bruelheide, Jürgen Dengler, Ute Jandt, Florian Jansen, Ricarda Pätsch & Milan Chytrý
1. Niche filtering predicts that abundant species in communities have similar traits that are suitable for the environment. However, niche filtering can operate on distinct axes of trait variation in response to different ecological conditions. Here, we use a trait-based approach to infer niche filtering processes and (1) test if abundant and rare species in grassland communities are differently positioned along distinct axes of trait variation, (2) determine if these trait variation axes, as well...

Electron Density Shift in Imidazolium Derivatives upon Complexation with Cucurbit[6]uril

Viktor Kolman, Radek Marek, Zora Strelcova, Petr Kulhanek, Marek Necas, Jan Svec & Vladimir Sindelar
Abstract In this study, we have investigated the supramolecular interaction between series of 1-alkyl-3-methylimidazolium guests with variable alkyl substituent lengths and cucurbit[6]uril (CB6) in...

Chiral Bambusurils for Enantioselective Recognition of Carboxylate Anion Guests

Jan Sokolov & Vladimir Sindelar
Abstract Synthesis of the first enantiomerically pure chiral bambusurils is reported. The bambusurils were prepared on the gram scale without using any chromatography techniques. The bambusurils fo...

Anion Binding Inside a Bambus[6]uril Macrocycle in Chloroform

Vaclav Havel & Vladimir Sindelar
Abstract Bambus[6]urils are a class of neutral anion receptors with outstanding binding properties in various solvents. The host–guest associations of bambusurils in aqueous environments have been ...

Functionalized Chiral Bambusurils: Synthesis and Host‐Guest Interactions with Chiral Carboxylates

Jan Sokolov, Adam Štefek & Vladimír Šindelář
Abstract Bambusurils are a class of macrocyclic anion receptors that exhibit notable anion recognition properties, able to bind various inorganic anions as well the carboxylates or sulfonates. Rece...

De novo developed microsatellite markers in gill parasites of the genus Dactylogyrus (Monogenea)

Michal Benovics, Lenka Gettová & Andrea Šimková
Approaches using microsatellite markers are considered the gold standard for modern population-genetic studies. However, though they have found application in research into various platyhelminth taxa, they remained substantially underutilized in the study of monogeneans. In the present study, a newly-developed set of 24 microsatellite markers was used to investigate the genetic diversity of the generalist monogenean species Dactylogyrus vistulae. The analyzed parasite specimens were collected from 13 cyprinoid species from 11 sites in the Apennine...

Water-mediated inclusion of benzoates and tosylates inside the bambusuril macrocycle

Angel E. Kaifer, Vaclav Havel, Vladimir Sindelar & Marek Necas
A supramolecular complex between benzoates and a bambusuril crystallizes out immediately after mixing in chloroform but only in the presence of residual water molecules. In this complex each of the two portals of the macrocycle is occupied by one benzoate. Carboxylate groups are connected through hydrogen bo

Registration Year

  • 2021
    42

Resource Types

  • Dataset
    42

Affiliations

  • Masaryk University
    42
  • Department of Physical and Technical Sciences
    11
  • University of Miami
    8
  • University of the Basque Country
    3
  • Central European Institute of Technology
    3
  • University of Vienna
    3
  • Martin Luther University Halle-Wittenberg
    3
  • University of Oviedo
    2
  • Aarhus University
    2
  • University of Picardie Jules Verne
    2